MODUL ANSWER
Preparation of a
solution by dilution (pg 128)
1(a) Standard solution is a solution in which its
concentration is accurately known.
(b) -molar mass of NaOH = 23+16+1 = 40 g mol-1
-
mol NaOH = 500 ×
1.0 /1000 = 0.5 mol
-
Mass of NaOH = 0.5 mol ×
40 g mol-1= 20.0 g
Preparation of 500 cm3
1.0 mol dm-3 sodium hydroxide
-
20.0 g weighing
bottle
-
20.0 g distilled
water
-
Volumetric flask
-
Rinse distilled
water volumetric flask
-
Distilled water volumetric
flask calibration mark
-
Volumetric flask stopper inverted
Calculate the volume
of 1 mol dm-3 sodium hydroxide used:
-
M2
× V2 =
0.1 × 250 = 25 cm3
M1 1
Preparation of 250 cm3 1.0 mol dm-3 sodium
hydroxide
-
25 cm3
-
25 cm3 volumetric flask
-
Distilled water volumetric
flask calibration mark
-
Volumetric flask stopper inverted
1(a) (i)
weak acid : An acid that
partially ionizes in water to produce low concentration of hydrogen ion, H+.
Strong acid : An acid that
completely ionizes in water to produce high concentration of hydrogen ion, H+.
(ii)
-
higher
-
stong acid completely higher
-
weak acid partially
-
CH3COO- + H+
(iii)
-
higher lower
-
lower higher
b)
- molecules ionise molecules molecules neutral
Hydrogen
-
ionises partially ethanoate hydrogen
2a(i) solution P
(ii) solution U
b(i) Q
(ii) R
(iii) T
(iv) P
(v) U
(vi) S
c(i) P/Q/R and T/U
(ii) P/Q
3.
80 g dm-3
4.
0.5 mol dm-3
5.
2 mol dm-3
6.
10 g
7.
0.4 mol dm-3
8.
50 cm3
9.
a)
Number of mol of sulphuric acid
= 50 × 1
1000
= 0.05 mol
H2SO4 → 2H+ + SO42-
From the equation,
1 mol of H2SO4: 2 mol of H+
0.05 mol of H2SO4 : 0.1 mol of H+
|
Number of mol of hydrocloric acid
= 50 × 1
1000
= 0.05 mol
HCl →
H+ + Cl-
From the equation,
1 mol of HCl: 1 mol of H+
0.05
mol of HCl : 0.05 mol of H+
|
The
number of H+ in 50 cm3
of 1 mol dm-3 of sulphuric acid is twice of the number of in 50 cm3
of 1 mol dm-3 of hydrochloric acid.
|
|
Sulphuric
acid is diprotic acid whereas hydrochloric acid is monoprotic acid.
1 mol of sulphuric acid ionises to 2 mol of H+ whereas 2 mol of hydrochloric acid ionizes to
1 mol of H+ . The number of H+ in the same volume and same concentration is
doubled in sulphuric acid compared to hydrochloric acid.
|
b) 100
cm3